Study of SO<sub>2</sub> Adsorption on Porous SiO<sub>2</sub> Particles Using a Micro-Reactor System

Yumei Wu; Xiaoling Zha; Jin Xu

doi:doi:10.11648/j.mc.20170503.12

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Study of SO₂ Adsorption on Porous SiO₂ Particles Using a Micro-Reactor System

Yumei Wu, Xiaoling Zha, Jin Xu

Published in Modern Chemistry (Volume 5, Issue 3)

Received: 14 May 2017 Published: 16 May 2017

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Abstract

Immobilized ionic liquids (ILs) with high selective adsorption capacity of SO₂ from N₂, on porous solid particles such as SiO₂, has potential applications on SO₂ emission control. As the first step towards the establishment of a comprehensive model for SO₂ adsorption on supported IL, the performance of neat SiO₂, the support material, was evaluated in this work. A series of adsorption/desorption breakthrough experiments were carried out using a micro-reactor system to investigate the effects of concentration, particle structure and temperature. Theoretical analyses of experimental observations were used to identify the adsorption mechanisms and relative importance of mass transfer processes.

Published in	Modern Chemistry (Volume 5, Issue 3)
DOI	10.11648/j.mc.20170503.12
Page(s)	43-49
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

SiO₂, SO₂ Capture, Mass Transfer Kinetics, Micro-Reactor

References

[1]	Lunt R. R and Cunic J. D. Profiles in Flue Gas Desulfurization. John Wiley & Sons, Inc., Hoboken, NJ, USA, 2000.
[2]	Srivastava R. K and Jozewicz W. Flue gas desulfurization: the state of the art. J Air Waste Manag Assoc. 2001; 51(12): 1676.
[3]	Camper D, Scovazzo P, Koval C, Noble R. Gas Solubilities in Room-Temperature Ionic Liquids. Ind Eng Chem Res. 2004; 43: 3049.
[4]	AnthonyJ. L, Maginn E. J, Brennecke J. F. Solubilities and Thermodynamic properties of Gases in the Ionic Liquid 1-n-Butyl-3-Methylimidazolium Hexafluorophosphate. J Phys Chem B. 2002; 106:7315.
[5]	Cadena C, Anthony J. L, Shah J. K, Morrow T. I, Brennecke J. F, Maginn E. J. Why Is CO₂ so Soluble in Imidazolium-Based Ionic Liquids. J Am Chem Soc. 2004; 126: 5300.
[6]	Bates E. D, Mayton R. D, Ntai I, Davis J. H. CO₂ Capture by a Task-Specific Ionic Liquid. J Am Chem Soc. 2002; 124: 926.
[7]	Zhang X, Zhang X. C, Dong H, Zhao Z, Zhang S, Huang Y. Carbon capture with ionic liquids: overview and progress. Energy Environ Sci. 2012; 5: 6668.
[8]	Scovazzo P, Camper D, Kieft J, Poshusta J, Koval C, Noble R. Regular Solution Theory and CO₂ Gas Solubility in Room-Temperature Ionic Liquids. Ind Eng Chem Res. 2004; 43: 6855.
[9]	Wu W. Z, Han B. X, Gao H. X, Liu Z. M, Jiang T, Huang J. Desulfurization of Fuel Gas: SO₂ Absorption by an Ionic Liquid. Angew Chem Int Ed. 2004; 43: 2415.
[10]	Huang J, Riisager A, Wasserscheid P, Fehrmann R. Reversible Physical Absorption of SO₂ by Ionic Liquids. Chem Commun. 2006; 38: 4027.
[11]	Huang J, Riisager A., Berg R. W, Fehrmann R. Tuning Ionic Liquids for High Gas Solubility and Reversible Gas Sorption. J Mol Cat A-Chem. 2008; 279: 170.
[12]	Yuan X. L, Zhang S. J, Lu X. M. Hydroxyl Ammonium Ionic Liquids: Synthesis, Properties and Solubility of SO₂. J Chem Eng Data. 2007; 52: 596.
[13]	Anderson J. L, Dixon J. K, Maginn E. J, Brennecke J F. Measurement of SO₂ solubility in Ionic Liquids. J Phys Chem B. 2006; 110: 15059.
[14]	Jiang Y. Y, Zhou Z, Jiao Z, Li L, Wu Y. T, Zhang Z. B. SO₂ Gas Separation Using Supported Ionic Liquid Membranes. J Phys Chem B. 2007; 111: 5058.
[15]	Yokozeki A, Shiflett M. B. Separation of carbon dioxide and sulfur dioxide gases using room-temperature ionic liquid [hmim]-[Tf2N]. Energy Fuels. 2009; 23:4701.
[16]	Huang J, Riisager A, Wasserscheid P, Fehrmann R. Reversible physical absorption of SO₂ by ionic liquids. Chem Commun.2006; 38: 4027.
[17]	Anderson J. L, Dixon J. K, Maginn E. J, Brennecke J. F. Measurement of SO₂ solubility in ionic liquids. J Phys Chem B. 2006; 110: 15059.
[18]	Wang C, Cui G, Luo X, Xu Y, Li H, Dai S. Highly efficient and reversible SO₂ capture by tunable azole-based ionic liquids through multiple-site chemical absorption. J Am Chem Soc. 2011; 133:11916.
[19]	Tang Y X, Mao W K, Ma N, et al. [Adsorption performances for sulfur dioxide using imidazole ionic liquids] [J]. Huan Jing Ke Xue, 2010, 31(31):2582-2586.
[20]	Qu Y, Lu. Adsorption of five adsorbents for different ionic liquids aqueous solutions [J]. Chinese Journal of Environmental Engineering, 2012, 6(9):2969-2973.
[21]	Wishart J F. Energy applications of ionic liquids [J]. Energy & Environmental Science, 2009, 2(9):956-961.
[22]	Wang C, Ren S, Hou Y, et al. Absorption of SO₂ in simulated flue gas with aqueous ionic liquid solutions [J]. Ciesc Journal, 2015, 66(S1):222-227.
[23]	Huang K, Lu J F, Wu Y T, et al. Absorption of SO₂, in aqueous solutions of mixed hydroxylammonium dicarboxylate ionic liquids [J]. Chemical Engineering Journal, 2013, s 215–216(2):36-44.
[24]	Xu J, Zha X, Wu Y, et al. Fast and highly efficient SO₂ capture by TMG immobilized on hierarchical micro-meso-macroporous AlPO-5/cordierite honeycomb ceramic materials [J]. Chemical Communications, 2016, 52(38):6367-6370.
[25]	Li X, Zhang L, Ying Z, et al. SO₂ Absorption Performance Enhancement by Ionic Liquid Supported on Mesoporous Molecular Sieve [J]. Energy & Fuels, 2015, 29(2):150105003334007.
[26]	Chen K, Lin W, Yu X, et al. Designing of anion‐functionalized ionic liquids for efficient capture of SO₂ from flue gas [J]. Aiche Journal, 2015, 61(6):2028-2034.
[27]	Wu L. B, An D, Dong J, Zhang Z. M, Li B-G, Zhu S-P. Preparation and SO₂ Absorption/Desorption Properties of Crosslinked Poly (1, 1, 3, 3-Tetramethylguanidinium Acrylate) Porous Particles. Macromol Rapid Commun. 2006; 27: 1949.
[28]	Zhang Z, Wu L, Dong J, Li B-G and Zhu S-P. Preparation and SO₂ Sorption/Desorption Behavior of an Ionic Liquid Supported on Porous Silica Particles. Ind Eng Chem Res. 2009; 48: 2142.
[29]	Li X, Zhang L, Zheng Y, Zheng Chuguang. SO₂ Absorption Performance Enhancement by Ionic Liquid Supported on Mesoporous Molecular Sieve. Energy Fuels 2015; 29: 942.
[30]	Jin M, Hou Y, Wu W, Ren S, Tian S, Xiao L, Lei Z. Solubilities and Thermodynamic Properties of SO₂ in Ionic Liquids. J Phys Chem B. 2011; 115: 6585.
[31]	H. S. Traub. Preparative Chromatography. Weinheim, Germany, 2005.
[32]	Zha X. Master Thesis at Wenzhou University.
[33]	Xu J, Zhu L, Xu G, Yu W, Ray A. K. Determination of competitive adsorption isotherm of enantiomers on preparative chromatographic columns using inverse method. J Chromatogr A. 2013; 1273: 49.
[34]	Bird R. B, Stewart W. E, Lightfoot E. N. Transport Phenomena. John Wiley & Sons, New York, 1960.
[35]	Gritti F, Guiochon G. Mass transfer kinetics, band broadening and column efficiency. J Chromatogr A. 2012; 1221: 2.

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APA Style

Yumei Wu, Xiaoling Zha, Jin Xu. (2017). Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Modern Chemistry, 5(3), 43-49. https://doi.org/10.11648/j.mc.20170503.12

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ACS Style

Yumei Wu; Xiaoling Zha; Jin Xu. Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Mod. Chem. 2017, 5(3), 43-49. doi: 10.11648/j.mc.20170503.12

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AMA Style

Yumei Wu, Xiaoling Zha, Jin Xu. Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Mod Chem. 2017;5(3):43-49. doi: 10.11648/j.mc.20170503.12

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@article{10.11648/j.mc.20170503.12,
  author = {Yumei Wu and Xiaoling Zha and Jin Xu},
  title = {Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System},
  journal = {Modern Chemistry},
  volume = {5},
  number = {3},
  pages = {43-49},
  doi = {10.11648/j.mc.20170503.12},
  url = {https://doi.org/10.11648/j.mc.20170503.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20170503.12},
  abstract = {Immobilized ionic liquids (ILs) with high selective adsorption capacity of SO2 from N2, on porous solid particles such as SiO2, has potential applications on SO2 emission control. As the first step towards the establishment of a comprehensive model for SO2 adsorption on supported IL, the performance of neat SiO2, the support material, was evaluated in this work. A series of adsorption/desorption breakthrough experiments were carried out using a micro-reactor system to investigate the effects of concentration, particle structure and temperature. Theoretical analyses of experimental observations were used to identify the adsorption mechanisms and relative importance of mass transfer processes.},
 year = {2017}
}

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TY  - JOUR
T1  - Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System
AU  - Yumei Wu
AU  - Xiaoling Zha
AU  - Jin Xu
Y1  - 2017/05/16
PY  - 2017
N1  - https://doi.org/10.11648/j.mc.20170503.12
DO  - 10.11648/j.mc.20170503.12
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 43
EP  - 49
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20170503.12
AB  - Immobilized ionic liquids (ILs) with high selective adsorption capacity of SO2 from N2, on porous solid particles such as SiO2, has potential applications on SO2 emission control. As the first step towards the establishment of a comprehensive model for SO2 adsorption on supported IL, the performance of neat SiO2, the support material, was evaluated in this work. A series of adsorption/desorption breakthrough experiments were carried out using a micro-reactor system to investigate the effects of concentration, particle structure and temperature. Theoretical analyses of experimental observations were used to identify the adsorption mechanisms and relative importance of mass transfer processes.
VL  - 5
IS  - 3
ER  -

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Author Information

Yumei Wu

Chemical Engineering Department, Wenzhou University, Wenzhou, China
Xiaoling Zha

Chemical Engineering Department, Wenzhou University, Wenzhou, China
Jin Xu

Chemical Engineering Department, Wenzhou University, Wenzhou, China

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APA Style

Yumei Wu, Xiaoling Zha, Jin Xu. (2017). Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Modern Chemistry, 5(3), 43-49. https://doi.org/10.11648/j.mc.20170503.12

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ACS Style

Yumei Wu; Xiaoling Zha; Jin Xu. Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Mod. Chem. 2017, 5(3), 43-49. doi: 10.11648/j.mc.20170503.12

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AMA Style

Yumei Wu, Xiaoling Zha, Jin Xu. Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System. Mod Chem. 2017;5(3):43-49. doi: 10.11648/j.mc.20170503.12

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@article{10.11648/j.mc.20170503.12,
  author = {Yumei Wu and Xiaoling Zha and Jin Xu},
  title = {Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System},
  journal = {Modern Chemistry},
  volume = {5},
  number = {3},
  pages = {43-49},
  doi = {10.11648/j.mc.20170503.12},
  url = {https://doi.org/10.11648/j.mc.20170503.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20170503.12},
  abstract = {Immobilized ionic liquids (ILs) with high selective adsorption capacity of SO2 from N2, on porous solid particles such as SiO2, has potential applications on SO2 emission control. As the first step towards the establishment of a comprehensive model for SO2 adsorption on supported IL, the performance of neat SiO2, the support material, was evaluated in this work. A series of adsorption/desorption breakthrough experiments were carried out using a micro-reactor system to investigate the effects of concentration, particle structure and temperature. Theoretical analyses of experimental observations were used to identify the adsorption mechanisms and relative importance of mass transfer processes.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Study of SO2 Adsorption on Porous SiO2 Particles Using a Micro-Reactor System
AU  - Yumei Wu
AU  - Xiaoling Zha
AU  - Jin Xu
Y1  - 2017/05/16
PY  - 2017
N1  - https://doi.org/10.11648/j.mc.20170503.12
DO  - 10.11648/j.mc.20170503.12
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 43
EP  - 49
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20170503.12
AB  - Immobilized ionic liquids (ILs) with high selective adsorption capacity of SO2 from N2, on porous solid particles such as SiO2, has potential applications on SO2 emission control. As the first step towards the establishment of a comprehensive model for SO2 adsorption on supported IL, the performance of neat SiO2, the support material, was evaluated in this work. A series of adsorption/desorption breakthrough experiments were carried out using a micro-reactor system to investigate the effects of concentration, particle structure and temperature. Theoretical analyses of experimental observations were used to identify the adsorption mechanisms and relative importance of mass transfer processes.
VL  - 5
IS  - 3
ER  -

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